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Asymmetric Synthesis and Application of alpha-Amino Acids

9780841269743
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Description
Asymmetric Synthesis and Application of alpha-Amino Acids contains 28 top-notch chapter-reviews on the most advanced methodological developments in the science of asymmetric synthesis of alpha-amino acids. Special emphasis is given to the catalytic asymmetric synthesis and industrial-scale synthesis of alpha-amino acids. The book has been designed to be a comprehensive snap-shot of current research activity in the field reviewed by internationally renowned experts fromacademic and industrial laboratories around the world. The general topics covered in the book include three major synthetic approaches:: Stoichiometric; Catalytic and Enzymatic Approaches as well as two chapters by application of alpha-amino acids for total synthesis of complex natural compounds and one chapteron the currently most advanced approach in peptide synthesis. A substantial amount of the data reviewed in the book has never been published. In particular, cutting-age technology currently being used in industry for truly large-scale preparation of enantiomerically pure alpha-amino acids, summarized in the book, will give the reader unprecedented perspective on advanced synthetic methods which will shape the pharmaceutical market in the near future. Taking into account the significant impactthat alpha-amino acids have on nearly all aspects of modern life and chemical industry, this book is expected to be a prime reference in the field and of interest to a truly diverse readership.
Product Details
OUP USA
83717
9780841269743
9780841269743

Data sheet

Publication date
2009
Issue number
1
Cover
hard cover
Pages count
504
Dimensions (mm)
158 x 236
Weight (g)
798
  • I. Stoichiometric Approach; Recent Developments in the Application of Organometallic Chemistry to Amino Acid Synthesis; Synthesis of Heterocycle-Linked C-Glycosyl Amino Acids and C-Glycopeptides; Asymmetric Synthesis of Amino Acids with a Tetrasubstituted Carbon Center via Memory of Chirality; Asymmetric Synthesis of ?-Substituted ?-Amino Acids:: Strecker and Claisen Approaches; Michael Addition Reactions between Nucleophilic Glycine Equivalents and Acrylic Acid Derivatives as a Practical and Generalized Approach to the Asymmetric Synthesis of ?-Substituted-?-Amino Acids; Novel Chiral Template for Preparation of ?-Amino Acids; II. Catalytic Approach; Catalytic Enantioselective Synthesis of ???-Disubstituted Amino Acids:: the Strecker Reaction of Ketimines Using Chiral Poly-Gadolinium Complexes; Asymmetric Amino Acid Synthesis by the Asymmetric Alkylation of Glycine Derivatives with Chiral Spiro-Type and Simplified Phase Transfer Catalysts; Catalytic asymmetric synthesis of ?-amino acid derivatives; approaches toward green sustainable methodology for preparation of optically active amino acids; Transition metal catalyzed reactions towards the synthesis of amino acids and peptides; Development of Phase-Transfer-Catalyzed Asymmetric Strecker Reaction Based on the Molecular Design of Chiral Quaternary Ammonium Salts; Efficient Synthesis of ?-Amino Acids via Organoboronate Reagents; Synthesis of Amino Acid Derivatives via Asymmetric Hydrogenation; Stereoselective Synthesis of anti-?-Hydroxy-?-Amino Acids using anti-Selective Asymmetric Hydrogenation; Catalyst Screening for the Synthesis of Amino Acids; Asymmetric Synthesis of a-Amino Acids using Polymer-Supported Cinchona Ammonium Salts as Phase-Transfer Catalysts; Practical synthesis of chiral a-amino acids by kinetic resolution of urethane-protected a-amino acid N-carboxyanhydrides with modified chinchona alkaloid catalysts; Asymmetric Stereoselective Synthesis of Quaternary, a-Vinyl Amino Acids and their a-(2Z-Fluoro)vinyl Congeners - Promising Candidates for PLP Enzyme Inactivation; III. Enzymatic Approach; Preparation of Chiral Amino Acid Intermediates for Synthesis of Pharmaceutical Compounds using Amino Acid Dehydrogenases; Chemo-Enzymatic Synthesis of Unnatural Amino Acids; Integrated Solutions of Non-natural Amino Acids; Enzymatic Synthesis of Unnatural Amino Acids; Production of amino acids using wild type and recombinant whole cell catalysts:: Using Platform Technologies for Enhancing Production Efficiency; Synthesis of Optically Active ?-Methyl Amino Acids using Biotransformation as a Key Step; A Novel Synthetic Method of Amino Acids in the Cell Factory; IV. Application of Enantiomerically Pure ?-Amino Acids in the Total Synthesis of Complex Natural Products and Peptides; New Tricks in Amino Acid Synthesis:: Applications to Complex Natural Products; ?-Substituted d-Leucines and their Relevance in the Total Synthesis of Natural and Non-Natural Aeruginosins; Pure Peptides via Fluorocarbon Capping Technology:: A Hands-On Discussion;
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