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Science of Synthesis: Cross-Dehydrogenative Coupling

Science of Synthesis: Cross-Dehydrogenative Coupling

9783132455245
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15 308,95 zł Zniżka 1 700,99 zł Brutto
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Opis

Comprehensive overview of strategies and applications of cross-dehydrogenative coupling methods

Cross-Dehydrogenative Coupling (CDC) represents a type of coupling reaction for the construction of a C-C bond or C-heteroatom (C-X) bond directly from C-H and X-H bonds present in the precursors. Since this genre of coupling reaction obviates the need for substrate prefunctionalization, it has an added advantage of high efficiency, atom economy, and environmental friendliness. CDC reactions are triggered by transition-metal catalysts or simply by an oxidants, or by either photocatalysis or electrocatalysis, leading to a hetero- or homo-coupled products with the removal of two hydrogens. Over the years, several CDC strategies have been developed that has made it possible to construct bonds between carbon-hydrogen (C-H) bonds of diverse hybridization. CDC has also streamlined the synthesis and functionalization of various nitrogen, oxygen, and sulfur-containing heterocycles. This volume features a series of chapters systematically covering methods and strategies in CDC, organized primarily on the type of bond being formed. In addition, particular aspects of CDC are highlighted in devoted chapters on topics such as mechanistic aspects, electrochemical and flow methods, transformations in water, natural product synthesis, and enantioselective protocols.

Szczegóły produktu
Georg Thieme
100860
9783132455245
9783132455245

Opis

Rok wydania
2023
Numer wydania
1
Oprawa
twarda
Liczba stron
680
Wymiary (mm)
170.18 x 255.27
Waga (g)
1432

  • 1 Introduction
    2 Cross-Dehydrogenative Coupling: Development and Perspectives
    3 Mechanistic Aspects of Transition-Metal-Catalyzed and Non-Transition-Metal-Mediated Cross-Dehydrogenative Coupling
    4 Cross-Dehydrogenative Coupling Involving Alkynes for C(sp2)—C(sp) Bond Formation
    5 (Het)Arene/(Het)Arene Cross-Dehydrogenative Coupling for C(sp2)—C(sp2) Bond Formation
    6 (Het)Arene/Alkene Cross-Dehydrogenative Coupling for C(sp2)—C(sp2) Bond Formation
    7 Alkene/Alkene Cross-Dehydrogenative Coupling for C(sp2)—C(sp2) Bond Formation
    8 Cross-Dehydrogenative Coupling Involving Aldehydes for C(sp2)—C(sp2) Bond Formation
    9 (Het)Arene/Alkane Cross-Dehydrogenative Coupling for C(sp2)—C(sp3) Bond Formation
    10 Alkene/Alkane Cross-Dehydrogenative Coupling for C(sp2)—C(sp3) Bond Formation
    11 Cross-Dehydrogenative Coupling for C(sp3)—C(sp3) Bond Formation
    12 Electrochemical C—C Bond Formation through Cross-Dehydrogenative Coupling
    13 C—C Bond Formation in Flow Systems Through Cross-Dehydrogenative Coupling
    14 C—C Bond Formation in Water through Cross-Dehydrogenative Coupling
    15 C—C Bond Formation through Cross-Dehydrogenative Coupling in Natural Product and API Synthesis
    16 C—N Bond Formation through Cross-Dehydrogenative Coupling
    17 C—O Bond Formation through Cross-Dehydrogenative Coupling
    18 Heteroatom—Heteroatom Bond Formation through Cross-Dehydrogenative Coupling
    19 Enantioselective Cross-Dehydrogenative Coupling

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